Q.
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7cm3s−1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2cm3s−1. The gas is
According to Graham's law of diffusion, r2r1=ρ1ρ2
or r2r1=M1M2
Here, r1= diffusion rate of hydrogen =28.7cm3s−1. r2= diffusion rate of unknown gas =7.2cm3s−1. M1= molecular mass of hydrogen =2g ∴7.228.7=2M2 or M2=(7.228.7)2×2≃32g 32g is molecular mass of oxygen.