Q.
For the reaction, N2O5→2NO2+21O2 dt−d[N2O5]=k1[N2O5] dtd[NO2]=k2[N2O5] dtd[O2]=k3[N2O5]
The relation in between k1 , k2 and k3 is
The rate of reaction is given by dt−d[N2O5]=+21dtd[NO2]=+dt2d[O2]
Substituting the given values, we get k1[N2O5]=21k2[N2O5]=2k3[N2O5]
or k1=2k2=2k3
or 2k1=k2=4k3