For the raction :- 4KClO3 arrow 3KClO4+KCl if (- d [KClO3]/dt)=K1[KClO3]n (d [KClO4]/dt)=K2[KClO3]n (d [KCl]/dt)=K3[KClO3]n the correct relation between K1,K2 and K3 is :-

Question

For the raction :- 4KClO3 arrow 3KClO4+KCl if (- d [KClO3]/dt)=K1[KClO3]n (d [KClO4]/dt)=K2[KClO3]n (d [KCl]/dt)=K3[KClO3]n the correct relation between K1,K2 and K3 is :- (A) K1=K2=K3 (B) 4K1=3K2=K3 (C) 3K1=4K2=12K3 (D) 12K1=4K2=3K3

Tardigrade Admin · Accepted Answer

(1/4)((- d [(KClO)3]/dt))=(1/3)(d [(KClO)4]/dt)=(d [KCl]/dt) (K1/4)=(K2/3)=(K3/1) 3K1=4K2=12K3

Q. For the raction :-
$4 K Cl O_{3} \to 3 K Cl O_{4} + K Cl$
if $\frac{- d [ K Cl O _{3} ]}{d t} = K_{1} [K Cl O_{3}]^{n}$
$\frac{d [ K Cl O _{4} ]}{d t} = K_{2} [K Cl O_{3}]^{n}$
$\frac{d [ K Cl ]}{d t} = K_{3} [K Cl O_{3}]^{n}$
the correct relation between $K_{1}, K_{2}$ and $K_{3}$ is :-

$K_{1} = K_{2} = K_{3}$

$4 K_{1} = 3 K_{2} = K_{3}$

$3 K_{1} = 4 K_{2} = 12 K_{3}$

$12 K_{1} = 4 K_{2} = 3 K_{3}$

$\frac{1}{4} (\frac{- d [ ( K ClO ) _{3} ]}{d t}) = \frac{1}{3} \frac{d [ ( K ClO ) _{4} ]}{d t} = \frac{d [ K Cl ]}{d t}$
$\frac{K _{1}}{4} = \frac{K _{2}}{3} = \frac{K _{3}}{1}$
$3 K_{1} = 4 K_{2} = 12 K_{3}$

Q. For the raction :- 4KClO3​→3KClO4​+KCl if dt−d[KClO3​]​=K1​[KClO3​]n dtd[KClO4​]​=K2​[KClO3​]n dtd[KCl]​=K3​[KClO3​]n the correct relation between K1​,K2​ and K3​ is :-

K1​=K2​=K3​

4K1​=3K2​=K3​

3K1​=4K2​=12K3​

12K1​=4K2​=3K3​