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Question
Chemistry
For an isothermal free expansion of an ideal gas into vacuum, which one of the following set correct?
Q. For an isothermal free expansion of an ideal gas into vacuum, which one of the following set correct?
1504
189
Thermodynamics
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A
Δ
U
=
0
,
q
>
0
,
w
<
0
23%
B
Δ
U
=
0
,
q
>
0
,
w
=
0
15%
C
Δ
U
=
0
,
q
=
0
,
w
=
0
51%
D
Δ
U
<
0
,
q
=
0
,
w
<
0
10%
Solution:
For isothermal process,
Δ
T
=
0.
For an ideal gas, internal energy U depend only on temperature.
So,
Δ
U
=
0
Now
Δ
U
=
q
+
w
q
=
−
w
=
P
Δ
U
For free expansion
P
ext
=
0
So,
q
=
−
w
=
0
∴
Δ
U
=
0
,
q
=
0
,
w
=
0