The energy for nth orbit in the atom of atomic number (Z) is given by En=n2Z2E0 So, for helium (Z = 2) and n = 3 ∴ for third orbit E3=94E0 ?(1) Now for H atom (Z = 1) and n = 2 ∴ for second orbit E2=41E0 ?(2) Now from Eqs. (1) and (2), we obtain E2E3=41E094ε0=916 or E3=916E2=916E