Q.
Dissociation constants of CH3COOH and NH4OH in aqueous solution are are almost same (10−5) . If pH of a CH3COOH solution is 3, what will be the pH of NH4OH ?
pH of CH3COOH
Sol =3
So [H3O+]=c×Ka=10−3
or 10−3=c×10−5
or c=10−1 M Kb=Ka=10−5
pH of 10−3 M
Solution of NH4OH [OH−]=c×Kb =10−1×10−5=10−3
pOH =3
or pH=14−3=11