Q. Assertion : The normal boiling point of water is and standard boiling point of water is .
Reason: The temperature at which vapour pressure of liquid is equal to the external pressure is called boiling temperature at that pressure.

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Solution:

At atm pressure, boiling temperature is called normal boiling point and if pressure is bar then the boiling point is called standard boiling point of the liquid. bar pressure is slightly less than atm pressure therefore, standard boiling point of the liquid is slightly lower than the normal boiling point.