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Question
Chemistry
Assertion: p-chlorobenzoic acid is stronger acid than benzoic acid. Reason: Chlorine has electron donating resonance (+ R ) effect.
Q.
Assertion
:
p
-chlorobenzoic acid is stronger acid than benzoic acid.
Reason
: Chlorine has electron donating resonance
(
+
R
)
effect.
3028
206
AIIMS
AIIMS 2013
The p-Block Elements - Part2
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A
Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
B
Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
C
Assertion is true but Reason is false.
D
Both Assertion and Reason are false.
Solution:
Chlorine has electron donating resonance effect however its inductive effect
(
−
I
)
wins over resonance effect and makes it overall electron withdrawing due to which increases the acid strength of benzoic acid.