Q. Assertion : One mole of NaCl contains 6.023 × 1023 molecules of sodium chloride.
Reason : 58.5 g of NaCl also contains 6.023 × 1023 molecules of NaCl.

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Solution:

Molar mass or mass of 1 mole of NaCl
= 23 + 35.5 = 58.5 g
According to mole concept,
1 mole of molecules = Gram molecular mass
= 6.023 × 1023 molecules
∴ 58.5 g of NaCl also contains 6.023 × 1023 molecules of NaCl.