Q. Assertion : o-Nitrophenol is more volatile than p-nitrophenol
Reason : Intramolecular hydrogen bonding is present in o-nitrophenol while intermolecular H - bonding is in p-nitrophenol.

 3214  208 AIIMSAIIMS 2001Alcohols Phenols and Ethers Report Error

Solution:

-Nitrophenol has higher boiling point than -nitrophenol, because intermolecular hydrogen bonding present in -nitrophenol is responsible for it. But intramolecular hydrogen bonding in -nitrophenol does not effect boiling point.