Q. Assertion : In the absence of an externally applied electric field, the displacement per unit volume of a polar dielectric material is always zero.
Reason : In polar dielectrics, each molecule has a permanent dipole moment but these are randomly oriented in the absence of an externally applied electric field.

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Solution:

The displacement vector is given by
where
applied electric field and
polarisation or dipole moment per unit volume
is the component of dipole moment of each molecule in direction and is the no. of molecules per unit volume]
Now in the absence of an electric field the polarisation vector vanishes (because is there if is there).
Therefore displacement