Tardigrade
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Tardigrade
Question
Chemistry
Assertion: F - F bond has low bond dissociation energy. Reason: The fluorine has lower reactivity.
Q.
Assertion :
F - F bond has low bond dissociation energy.
Reason :
The fluorine has lower reactivity.
2746
233
AIIMS
AIIMS 2002
The p-Block Elements - Part2
Report Error
A
If both assertion and reason are true and reason is a correct explanation of the assertion
0%
B
If both the assertion and reason are true but the reason is not a correct explanation of the assertion
25%
C
If the assertion is true but the reason is false
50%
D
If both the assertion and reason are false
25%
Solution:
Lower value of bond dissociation energy of fluorine is due to the high inter electronic repulsions between nonbonding electrons of the
2
p
-orbital of small sized fluorine. As a result
F
−
F
bond is weaker as comparison to
Cl
−
Cl
and
B
r
−
B
r
bonds.
Bond dissociation energy
F
−
F
38
Kc
a
l
/
m
o
l
e
Cl
−
Cl
57
K
c
a
l
/
m
o
l
e
B
r
−
B
r
45.5
Kc
a
l
/
m
o
l
e
I
−
I
,
35.6
K
c
a
l
/
m
o
l
e