Q. Assertion: Acetone and aniline shows negative deviations.
Reason: H-bonding between acetone and aniline is stronger than that between acetone-acetone and aniline-aniline.

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Solution:

Hydrogen bonding between acetone and aniline is stronger as compared to acetone and aniline - aniline. This is why acetone and aniline shows negative deviations.