Q. Arrange the following in increasing order of acidic strength.Chemistry Question Image

 194  163 Organic Chemistry – Some Basic Principles and Techniques Report Error

Solution:

I is least acidic due to the absence of any electron withdrawing group on ring. IV is most acidic due to the electron withdrawing resonance effect of from ortho-position, although intramolecular H-bonding decreases acidic strength to some extent. III is less acidic than II due to the steric inhibition of resonance of by two adjacent methyl groups.