Q.
An ideal gaseous mixture of ethane (C2H6) and ethene (C2H4) occupies 28 litre at 1atm and 273K. The mixture reacts completely with 128gO2 to produce CO2 and H2O. Mole fraction at C2H6 in the mixture is:
C2H6+3.5O2→2CO2+3H2O C2H4+3O2→2CO2+2H2O
Let volume of ethane is x litre. 22.4×4=3.5x+3(28−x) ⇒x=11.2 litre
at constant T and P,V∝n ⇒ Mole fraction of C2H6 in mixture =2811.2=0.4