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Question
Chemistry
Amongst the trihalides of nitrogen, which one is least basic?
Q. Amongst the trihalides of nitrogen, which one is least basic?
3017
183
IIT JEE
IIT JEE 1987
The p-Block Elements - Part2
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A
N
F
3
65%
B
NC
l
3
7%
C
NB
r
3
7%
D
N
I
3
21%
Solution:
The electron withdrawing inductive effect of halogen decreases electron density on nitrogen, lowers basic strength. Since, fluorine is most electronegative,
N
F
3
is least basic.