Q.
A thermodynamic process is shown in figure. In process ab,600J of heat is added, and in process bd 200J of heat is added. The total heat added in process acd is
There is no volume change in process ab,
so W=0 Process bd occurs at constant pressure,
so the work done by the system is W=P(V2−V1) =(8×104Pa)(5×10−3m3−2×10−3m3)=240J
Thus the total work for abd is W=240J
and the total heat for abd is Q=800J. ∴ΔU=Q−W=800J−240J=560J
Because ΔU is independent of path, the internal energy change is the same for path acd as for abd, that is, 560J.
The total work for path acd is W=(3×104Pa)(5×10−3m3−2×10−3m3)=90J ∴ Total heat added in the path acd is Q=ΔU+W=560J+90J=650J