Let the radius of small water droplet is r
Volume of one small water droplet, V=34πr3
Total volume =nV=64×34πr3(∵n=64)
Volume of larger drop =34πR3 ∴34πR3=64×34πr3 ⇒R=4r
Surface energy of one small droplet =S(4πr2)
Surface energy of large droplet =S(4πR2)
Required ratio =S(4πR2)64×S(4πr2) =R264r2 =16r264r2 =4:1