Q.
10 g of hydrofluoric acid gas occupies 5.6 L of volume at STP. If the empirical formula of the gas is HF, then its molecular formula in the gaseous state will be
2532
212
Some Basic Concepts of Chemistry
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Solution:
Mol. mass = mass of 22.4 L at STP =5.610×22.4=4 E.F. mass of HF=1+19=20.
Hence n=2040=2 ∴ Molecular formula = (Empirical formula)n =(HF)2=H2F2