Q.
0.5 g of an organic compound on Kjeldahl’s analysis gave enough ammonia to just neutralize 10 cm3 of 1 M H2SO4. The percentage of nitrogen in the compound is
1631
188
Organic Chemistry – Some Basic Principles and Techniques
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Answer: 56
Solution:
1 M of 10 ml H2SO4=1 M of 20 ml of NH3 1000 ml of 1 M ammonia contain =14 g of nitrogen 20 ml of 1 M ammonia contain =100014×20g of nitrogen =100014×20×0.5100=56.0%