Q.
0.078g of hydrocarbon occupies 22.4ml of volume at 1 atm and 0∘C. The empirical formula of the hydrocarbon is CH. The molecular formula is:
290
143
Some Basic Concepts of Chemistry
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Solution:
22.4mL of hydrocarbon weighs 0.078g
Then, 22400mL of hydrocarbon weighs =22.40.078×22400g =78g= molar mass
Emprical mass = at. mass of C+ at. mass of H =12+1=13g n=1378=6 ∴M.F=(E⋅F)n=(CH)6
or C6H6